Nickel(III) oxides are often poorly characterized and are assumed to be nonstoichiometric compounds.
Electron energy loss spectroscopy analysis related to structural changes is performed for the entire primary particle area to visualize the oxidation state of transition‐metal ions in two dimensions. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. For applications in organic chemistry, nickel oxides or peroxides are generated in situ and lack crystallographic characterization.
The oxidation state of nickel is 3+. Use the link below to share a full-text version of this article with your friends and colleagues. DOI: 10.1002/smll.201701802. EINECS 238-032-4 Published by ELSEVIER B.V. and Science Press. Gary W. Morrow "Nickel(II) Peroxide" Encyclopedia of Reagents for Organic Synthesis, 2001 John Wiley & Sons.
Among the various cathode materials, high‐Ni cathode materials enable a high energy density.
We demonstrate how by taking better account of electron correlations in the 3d shell of metal ions in nickel oxide it is possible to improve the description of both electron energy loss spectra and parameters characterizing the structural stability of the material compared with local spin density functional theory. Nickel oxide hydroxide is the inorganic compound with the chemical formula NiO(OH). Doping and surficial modification are considered key measures to address these drawbacks. Similarly it catalyzes the double oxidation of 3-butenoic acid to fumaric acid: Except where otherwise noted, data are given for materials in their.
and you may need to create a new Wiley Online Library account. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. He is now under joint-supervision by Prof. Jingbi You at Institute of Semiconductors, Chinese Academy of Sciences. This study systematically investigates the degradation of a high‐Ni cathode by comparing the chemical, structural, and electrical changes in pristine and 500 times‐cycled cathodes. Nickel oxide hydroxide is the inorganic compound with the chemical formula NiO(OH). However, the low electric conductivity and the mismatched energy level alignment of NiOx have restricted the efficiency of NiOx based device.
His research interests include the low dimensional semiconductor and ferroelectric perovskite and light-sensitive perovskite. The conceptually simple structure is commonly known as the rock salt structure. Degradation of High‐Nickel‐Layered Oxide Cathodes from Surface to Bulk: A Comprehensive Structural, Chemical, and Electrical Analysis. Please check your email for instructions on resetting your password. For example, "nickel peroxide" (CAS# 12035-36-8) is also closely related to or even identical with NiO(OH). Finally, we will discuss current challenges of utilizing NiOx HTLs in PSCs and attempt to give probable solutions to make further development in efficient as well as stable NiOx based PSCs. We use cookies to help provide and enhance our service and tailor content and ads.
Nickel oxide (NiOx) as p-type metal oxide, owning high charge mobility and intrinsic stability, has been widely adopted in inverted PSCs. It is a component of the nickel-metal hydride battery and of the nickel–iron battery. Dong‐Su Ko. The results imply that the observed monotonic capacity fade without unusual changes is due to the continuous formation of the Ni2+ phase from the surface to the bulk through chemical and structural degradation. However, the low electric conductivity and the mismatched energy level alignment of NiOx have restricted the efficiency of NiOx based device. Doping and surficial modification are … Jun‐Ho Park. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, I have read and accept the Wiley Online Library Terms and Conditions of Use. Cathode degradation remains poorly understood; the majority of studies have only explored the oxidation states of transition‐metal ions in localized areas and have rarely evaluated chemical degradation in complete particles after prolonged cycling. Surface/Interfacial Structure and Chemistry of High-Energy Nickel-Rich Layered Oxide Cathodes: Advances and Perspectives. Charge transporting layer, especially hole transporting layer is crucial for efficient inverted PSCs. Structure.
He is currently a graduate student under the supervision of Prof. Haoshuang Gu in Faculty of Physics and Electronic Sciences of Hubei University. Currently, he is a professor in Faculty of Physics and Electronic Sciences of Hubei University. Structure, properties, spectra, suppliers and links for: Nickel(II) oxide, 1313-99-1. O. Glemser "β-Nickel(III) Hydroxide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. It is a black solid that is insoluble in all solvents but attacked by base and acid. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Nickel oxide for inverted structure perovskite solar cells. Nickel oxide is a promising hole transporting material for stable perovskite solar cells. Analytical Engineering Group, Samsung Advanced Institute of Technology, 130 Samsung‐ro, Suwon, Gyeonggi‐do, 16678 Republic of Korea . Nickel tungstate. Small 2017, 13 (45) , 1701802. Casas-Cabanas, M.; Canales-Vazquez, J.; Rodriguez Carvajal, J.; Palacin, M.R. Any queries (other than missing content) should be directed to the corresponding author for the article. © 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Working off-campus? https://doi.org/10.1016/j.jechem.2020.04.027. Nickel(III) oxides are often poorly characterized and are assumed to be nonstoichiometric compounds. Multiple applications of lithium‐ion batteries in energy storage systems and electric vehicles require highly stable electrode materials for long‐term battery operation. The emergence of inverted perovskite solar cells (PSCs) has attached great attention derived from the potential in improving stability. Learn about our remote access options, Analytical Engineering Group, Samsung Advanced Institute of Technology, 130 Samsung‐ro, Suwon, Gyeonggi‐do, 16678 Republic of Korea, Next Generation Battery Research Center, Korea Electrotechnology Research Institute (KERI), 12, Bulmosan‐ro 10 beon‐gil, Seongsan‐gu, Changwon‐si, Gyeongsangnam‐doo, 51543 Republic of Korea, R&D Center, Samsung SDI, 130 Samsung‐ro, Suwon, Gyeonggi‐do, 16678 Republic of Korea, Materials Science and Engineering Program & Texas Materials Institute, University of Texas Austin, Austin, TX, 78712 USA, Beamline Department, PLS‐II, Pohang Accelerator Laboratory, 80, Jigok‐ro‐127‐beongil, Pohang, Gyeongsangbuk‐do, 37673 Republic of Korea, Department of Materials Science and Engineering, Seoul National University, 1 Gwanak‐ro, Gwanak‐gu, Seoul, 08826 Republic of Korea, E‐mail: ch1.jung@samsung.com, manth@austin.utexas.edu. 1. p. 1549. https://en.wikipedia.org/w/index.php?title=Nickel_oxide_hydroxide&oldid=978304580, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 14 September 2020, at 03:08. Jingbi You is currently a full professor in the Institute of Semiconductors, Chinese Academy of Sciences (ISCAS). in Hubei University. By continuing you agree to the use of cookies.
[2] It can be prepared by the reaction of nickel(II) hydroxide with aqueous potassium hydroxide and bromine as the oxidant:[3], Nickel(III) oxides catalyze the oxidation of benzyl alcohol to benzoic acid using bleach:[4]. Weifeng Huang, Augusto Marcelli, Dingguo Xia. High performance over 20% efficiency has been achieved on NiOx base inverted PSCs. Like many other binary metal oxides, NiO is often non-stoichiometric, meaning that the Ni:O ratio deviates from 1:1. [1], Its layered structure resembles that of the brucite polymorph of nickel(II) hydroxide, but with half as many hydrogens. Learn more. If you do not receive an email within 10 minutes, your email address may not be registered, Fei Ma received his B.S.
All rights reserved. Copyright © 2020 Elsevier B.V. or its licensors or contributors. Nickel(III) oxide (Ni2O3) has not been verified crystallographically. It is a component of the nickel-metal hydride battery and of the nickel–iron battery. Herein, we have summarized recent progresses and strategies on the NiOx based PSCs, including the synthesis or deposition methods of NiOx, doping and surface modification of NiOx for efficient and stable PSCs. Edited by G. Brauer, Academic Press, 1963, NY.
Haoshuang Gu received his Ph.D. from Huazhong University of Science and Technology. Nickel tungsten tetraoxide. Search for more papers by this author.